Radioactive Decay
In 1898, Marie Curie in Paris isolated polonium and radium from 10 tonnes of pitchblende ore. She measured the half-life of Ra-226 as 1,600 years (modern value: 1,599 ± 4 years) using an electroscope to measure the ionisation rate of the emitted radiation. She coined the term "radioactivity" and became the first scientist to win two Nobel Prizes — Physics in 1903 and Chemistry in 1911. Her quantitative electroscope method established the experimental framework for measuring radioactive decay that is still used today.
Practise this lesson
Four printable worksheets that build from the foundations up to exam-style questions — start at whatever level suits you.
A radioactive sample has a half-life of 10 minutes. You start with 1000 atoms.
Before reading on, answer:
- How many atoms remain after 10 minutes? After 20 minutes?
- Why can't we predict which specific atom will decay next?
- What does the decay rate depend on?
Warm-up: In alpha decay, an alpha particle is identical to:
Know — Decay Modes
- Alpha, beta, gamma
- Conservation laws
- Decay equations
Understand — Exponential Decay
- Half-life and decay constant
- Activity and count rate
- Carbon dating
Can Do — Calculate Decay
- Use $N = N_0 e^{-\lambda t}$
- Calculate half-life
- Analyse decay chains
Core Content
Alpha, beta, and gamma
Place a small sample of radium-226 in front of a Geiger counter. The counter clicks spontaneously — at random intervals — yet if you measure the total count rate for 10 minutes and again in 100 years, the average rate will decrease by exactly the factor predicted by t₁/₂ = 1,600 years, the value Marie Curie first determined in Paris in 1898. This spontaneous, probabilistic, yet statistically precise behaviour is the signature of radioactive decay. The three main decay modes differ in what the nucleus emits. Alpha decay ($\alpha$): A heavy nucleus emits an alpha particle ($^4_2\text{He}$), reducing its mass number by 4 and atomic number by 2:
$$^A_Z\text{X} \rightarrow \; ^{A-4}_{Z-2}\text{Y} + \; ^4_2\text{He}$$Alpha particles are massive and doubly charged, so they cause intense ionisation but have low penetration (stopped by paper or skin). They occur in very heavy nuclei ($Z > 82$) where the strong force is overwhelmed by Coulomb repulsion.
Beta-minus decay ($\beta^-$): A neutron converts to a proton, emitting an electron and an antineutrino:
$$n \rightarrow p + e^- + \bar{\nu}_e$$ $$^A_Z\text{X} \rightarrow \; ^A_{Z+1}\text{Y} + e^- + \bar{\nu}_e$$Beta particles are fast electrons with moderate penetration (stopped by a few mm of aluminium). Beta decay occurs when a nucleus has too many neutrons relative to protons.
Beta-plus decay ($\beta^+$) / Electron capture: A proton converts to a neutron, emitting a positron and neutrino (or capturing an orbital electron):
$$p \rightarrow n + e^+ + \nu_e$$ $$^A_Z\text{X} \rightarrow \; ^A_{Z-1}\text{Y} + e^+ + \nu_e$$This occurs when a nucleus has too many protons relative to neutrons.
Gamma decay ($\gamma$): An excited nucleus releases excess energy as a high-energy photon:
$$^A_Z\text{X}^* \rightarrow \; ^A_Z\text{X} + \gamma$$Gamma rays are highly penetrating (require several cm of lead or thick concrete) but cause less ionisation per unit path length than alpha or beta.
Figure 1 — Penetration comparison of alpha, beta and gamma radiation. Alpha is stopped by paper; beta by a few mm of aluminium; gamma requires several cm of lead.
Complete the decay equation: $^{238}_{92}\text{U} \rightarrow \; ^{234}_{90}\text{Th} + \; ?$ What type of decay is this?
Alpha (α): emits ⁴He, A−4, Z−2, stopped by paper. Beta-minus (β⁻): n→p+e⁻+ν̄_e, A unchanged, Z+1, stopped by Al. Beta-plus (β⁺): p→n+e⁺+ν_e, A unchanged, Z−1. Gamma (γ): excited nucleus emits photon, A and Z unchanged, requires lead. A and Z are conserved in every decay equation.
Write the table of decay types with changes to A and Z — you need to complete decay equations from memory in the HSC.
In alpha decay, the mass number of the daughter nucleus decreases by 4.
In beta-minus decay, the atomic number of the daughter nucleus decreases by 1.
Gamma decay does not change the mass number or atomic number of the nucleus.
Exponential decay and half-life
We just saw the three decay modes and what they each emit. That raises a question: how quickly does a sample decay, and can we predict how many nuclei remain at any future time? This card answers it → the exponential law N = N₀e^(−λt) exactly predicts population at any time, and the half-life t₁/₂ = ln2/λ is the key measurable quantity.
Radioactive decay is a random process at the individual nucleus level, but the statistical behaviour of a large sample follows a precise exponential law:
$$N = N_0 e^{-\lambda t}$$where $N$ is the number of remaining nuclei, $N_0$ is the initial number, $\lambda$ is the decay constant, and $t$ is time.
The half-life ($t_{1/2}$) is the time for half the nuclei to decay:
$$t_{1/2} = \dfrac{\ln 2}{\lambda} = \dfrac{0.693}{\lambda}$$The activity ($A$) is the number of decays per second:
$$A = \lambda N = \lambda N_0 e^{-\lambda t} = A_0 e^{-\lambda t}$$Activity is measured in becquerels (Bq), where 1 Bq = 1 decay per second. The older unit is the curie (Ci), where 1 Ci = $3.7\times10^{10}$ Bq.
After $n$ half-lives, the remaining fraction is $(1/2)^n$. For example, after 3 half-lives, $1/8$ of the original sample remains.
Carbon-14 dating: Living organisms maintain a constant $^{14}$C/$^{12}$C ratio. When they die, $^{14}$C decays with $t_{1/2} = 5{,}730$ years. Measuring the remaining $^{14}$C activity allows dating of organic materials up to ~50,000 years old.
Figure 2 — Exponential decay curve: after each half-life the number of remaining nuclei halves. The curve approaches zero but never reaches it — there is always a non-zero probability of a nucleus surviving.
$N = N_0 e^{-\lambda t}$ — number of remaining nuclei
$t_{1/2} = \ln(2)/\lambda = 0.693/\lambda$ — half-life
$A = \lambda N = A_0 e^{-\lambda t}$ — activity (Bq)
$N = N_0(1/2)^{t/t_{1/2}}$ — alternative half-life form
A sample has activity 800 Bq and half-life 6 hours. What is its activity after 24 hours? How many half-lives have passed?
Exponential decay: N = N₀e^(−λt), λ = ln2/t₁/₂. Half-life: t₁/₂ = 0.693/λ. Activity: A = λN (Bq). After n half-lives: fraction = (½)ⁿ. Carbon-14 dating: t₁/₂ = 5,730 yr; ¹⁴C/¹²C ratio falls after death; key assumption is atmospheric ratio constant.
Record the three forms of the decay equation and the half-life formula — switching between them cleanly is what separates Band 5 from Band 4 answers.
A sample has initial activity 400 Bq and half-life 2 hours. After 6 hours (3 half-lives), its activity in Bq is _____ Bq. Enter the numerical value.
A common exam trap: confusing activity with number of nuclei. Activity $A = \lambda N$ decreases exponentially just like $N$, but they are different quantities. When using $N = N_0(1/2)^{t/t_{1/2}}$, make sure $t$ and $t_{1/2}$ are in the same units. For decay equations, always check conservation of mass number ($A$) and atomic number ($Z$). In beta decay, an antineutrino ($\bar{\nu}_e$) is also emitted — don't forget it in complete equations. Gamma decay does not change $A$ or $Z$; it only releases energy. For carbon dating, the key assumption is that the atmospheric $^{14}$C/$^{12}$C ratio has been constant over time — this is approximately true but requires calibration.
Three of these statements about radioactive decay are correct. Pick the odd one out.
Activities
Practice writing decay equations and using $N = N_0(1/2)^n$
- Write the complete decay equation for $^{226}_{88}\text{Ra}$ undergoing alpha decay. Identify the daughter nucleus.
- Write the complete decay equation for $^{14}_6\text{C}$ undergoing beta-minus decay. Verify conservation of $A$ and $Z$.
- A sample of $^{32}\text{P}$ has a half-life of 14.3 days. If you start with $8.0 \times 10^{10}$ atoms, how many remain after 42.9 days?
- The activity of a sample drops from 3,200 Bq to 200 Bq in 4 hours. Calculate the half-life of the isotope.
Apply decay concepts to real-world contexts
- A wooden artefact has $^{14}$C activity of 6.25 Bq/g. Fresh wood has activity 50 Bq/g. Given $t_{1/2}(^{14}\text{C}) = 5{,}730$ years, estimate the age of the artefact. Show your working clearly.
- Describe one medical application of radioactive isotopes. State the type of radiation emitted and explain why that type is chosen for this application.
- Compare the biological danger of alpha radiation from an external source versus an internal source. Use ionisation and penetration properties in your answer.
- A student claims that after 10 half-lives, "all the radioactive atoms will have decayed." Evaluate this claim and correct any error.
A fresh five-question set drawn from this lesson's bank — feedback shown immediately. +5 XP per correct · +25 XP all correct
Pick your answer, then rate your confidence — that tells the system what to drill next.
ApplyBand 4(3 marks) 1. A sample of iodine-131 ($t_{1/2} = 8$ days) has an initial activity of 640 Bq. (a) Write an equation relating activity $A$ to the initial activity $A_0$, decay constant $\lambda$, and time $t$. (b) Calculate the activity after 24 days. (c) Explain why activity decreases with time, linking to the number of remaining nuclei.
1 mark: correct equation · 1 mark: correct activity · 1 mark: conceptual explanation
AnalyseBand 6(5 marks) 2. (a) Distinguish between alpha, beta-minus, and gamma decay, including the particles emitted and changes to $A$ and $Z$. (b) Write the complete decay equation for $^{238}_{92}\text{U}$ undergoing alpha decay. (c) A sample has initial activity 1,200 Bq and half-life 10 hours. Calculate its activity after 30 hours. (d) Explain why radioactive decay is described as a random process at the individual nucleus level but follows an exponential law for large samples. (e) Outline how carbon-14 dating is used to determine the age of organic materials and state one key assumption.
1 mark: decay modes table · 1 mark: U-238 equation · 1 mark: activity calculation · 1 mark: random vs statistical · 1 mark: C-14 dating + assumption
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Multiple choice
MC answers and full explanations are shown inline as you complete each question. Use the retry button to attempt a fresh set drawn from the lesson bank.
Short Answer — Model Answers
Q1 (3 marks): (a) $A = A_0 e^{-\lambda t}$ or equivalently $A = A_0(1/2)^{t/t_{1/2}}$ (1 mark). (b) 24 days = $24/8 = 3$ half-lives. $A = 640 \times (1/2)^3 = 640/8 = 80$ Bq (1 mark). (c) Activity $A = \lambda N$ — as nuclei undergo radioactive decay, the number of remaining radioactive nuclei $N$ decreases exponentially. Since activity is proportional to $N$, it also decreases exponentially with the same half-life (1 mark).
Q2 (5 marks): (a) Alpha: emits $^4_2\text{He}$ nucleus; $A$ decreases by 4, $Z$ decreases by 2. Beta-minus: emits $e^-$ and $\bar{\nu}_e$; $A$ unchanged, $Z$ increases by 1. Gamma: emits high-energy photon ($\gamma$); $A$ and $Z$ unchanged — only energy is released (1 mark). (b) $^{238}_{92}\text{U} \rightarrow ^{234}_{90}\text{Th} + ^4_2\text{He}$; check: $A$: $238 = 234 + 4$ ✓; $Z$: $92 = 90 + 2$ ✓ (1 mark). (c) $n = 30/10 = 3$ half-lives. $A = 1{,}200 \times (1/2)^3 = 1{,}200/8 = 150$ Bq (1 mark). (d) At the individual nucleus level, decay is a quantum mechanical, random process — we cannot predict when any specific nucleus will decay, only its probability per unit time ($\lambda$). However, for a large sample of $N$ nuclei, the law of large numbers ensures the aggregate rate of decay is predictable and follows the smooth exponential $N = N_0 e^{-\lambda t}$ (1 mark). (e) Living organisms continuously replenish $^{14}$C by metabolising atmospheric $\text{CO}_2$, maintaining a constant $^{14}$C/$^{12}$C ratio. When the organism dies, intake stops and $^{14}$C decays with $t_{1/2} = 5{,}730$ years. By measuring the remaining $^{14}$C activity relative to a modern standard, the age can be calculated using $A = A_0(1/2)^{t/t_{1/2}}$. Key assumption: the atmospheric $^{14}$C/$^{12}$C ratio has been approximately constant over the period being dated (1 mark).
At the start you were asked about Marie Curie's 1898 measurement in Paris: processing 10 tonnes of pitchblende to isolate 0.1 g of Ra-226, then measuring its half-life as 1,600 years using an electroscope — the same half-life used in today's nuclear medicine calculations. Review your predictions:
- Did you predict 500 atoms remain after one half-life and 250 after two? Correct — each t₁/₂ reduces the number by half: (½)¹ = 500, (½)² = 250 — the same exponential law Curie established from her Ra-226 ionisation rate measurements.
- Did you predict we cannot know which atom decays next because radioactive decay is a quantum mechanical, random process? Correct — individual decays are probabilistic and unpredictable, yet the aggregate follows Curie's precisely determined exponential law.
- Did you predict the half-life depends on the isotope but not on temperature, pressure, or chemical environment? Correct — $\lambda$ is an intrinsic nuclear property; this is why Curie could measure Ra-226's t₁/₂ = 1,600 years from a small sample in a Paris laboratory.
Extend: A sample of $^{131}$I ($t_{1/2} = 8$ days, used in thyroid cancer treatment) starts with $N_0 = 6.4\times10^{12}$ atoms. (a) Calculate the initial activity in Bq. (b) A patient receives a dose at $t = 0$. After 32 days, what fraction of the original activity remains? (c) Explain why a shorter half-life is generally preferable for radiotherapy isotopes used internally.
Five timed questions on radioactive decay. Beat the boss to bank a tier — gold (perfect + fast), silver (80%+), or bronze (cleared).
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